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Home > Chemistry and Molecular Modeling > Cyber Ed Multimedia Chemistry Courseware > Reaction Rates

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Learn why are some chemical reactions energetically favorable but very slow to happen?



Reaction Rates

Why are some reactions energetically favorable but very slow to happen? This question is answered in the program Reaction Rates. The general concept of rate is introduced with numerical examples and sets the stage for an understanding of reaction rates. Factors that affect reaction rates, such as temperature and concentration, are explained through the concepts of collision theory and activation energy. A step-by-step approach teaches rate laws and is reinforced with interactive lessons covering both rate constants and reaction order. The program also covers reaction mechanisms, including the rate-determining step. Throughout the program, videos and animations help students visualize what happens at the particle level and illustrate the incisive analogies.

OUTLINE:

I. Introduction

II. Rates of Reactions
A. The Concept of Rates
1. The Definition of Rate
2. Examples of Rates
3. Converting Units of Time
B. Reaction Rates
1. General Characteristics
2. Measuring the Change in Concentration
3. Stoichiometry and Reaction Rates
a. Determining Concentration Through Stoichiometry
4. Definition of Reaction Rate
a. Normalizing the Reaction Rate
5. Calculating Reaction Rate
6. Change in Reaction Rate as the Reaction Proceeds
7. Instantaneous vs. Average Rates

III. Factors Affecting Reaction Rates
A. Nature of Reactants
B. Temperature
C. Catalysts
1. Enzymes
D. Surface Area
E. Concentration

IV. Collision Theory
A. Kinetic Energy
1. Particles in a Sample Have Different Kinetic Energy
B. Activation Energy
1. A Visual Demonstration of Activation Energy
C. Why Increasing Temperature Increases Reaction Rates
D. The Activated Complex
E. Catalysts
1. Catalysts Lower
Activation Energy

V. Rate Laws
A. Rate is Proportional to the Concentration of Reactants
B. Definition of Rate Law
C. Calculating the Rate Constant
1. An Example
2. Another Example
D. Reaction Order
1. Determining Reaction Order
a. Example Using Sulfuryl Chloride
b. Example Using Hydrogen Iodide
c. Example Using Nitrogen Dioxide

VI. Reaction Mechanisms
A. Reactions Occur in Multiple Steps
B. The Steps of a Reaction Mechanism are Elementary Processes
C. An Example of a Reaction Mechanism
D. Rate Laws and Elementary Processes*
1. Determining Rate Laws From Elementary Processes*
E. The Rate-Determining Step
F. Evaluating Reaction Mechanisms*
1. An Example*
G. Conclusion
1. Reviewing the Reaction of Carbon Monoxide and Oxygen
2. Conclusion

*More advanced topics




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